The dilemma is this: Mobile phones, notebook computers, smart phones, and PDAs keep getting smaller, whilst their energy requirements grow. The batteries can’t keep up. Theoretically, lithium-sulfur batteries would be the energy source of choice, because they deliver significantly more energy - by mass - than conventional lithium-ion batteries.
However, their practical application suffers from the fact that their electrodes slowly dissolve, which results in a loss of capacity. Furthermore, lithium metal can form dendritic deposits that cause short circuits. This is why commercial “lithium” batteries do not contain lithium metal electrodes, but a material that can absorb and then release lithium ions, which is usually graphite. This type of lithium-ion cell supplies energy by transferring lithium ions only and delivers less energy.

The Italian researchers would like to combine the advantages of both types of battery to make long-lived, storable, safe, and easily produced high-capacity batteries. Their new type of lithium-metal-free cell uses a cathode (negative electrode) made of a carbon/lithium sulfide composite. The organic electrolyte solution is replaced by a lithium-ion-containing liquid enclosed in a gel-polymer membrane. The polymer shields the liquid from the electrodes. The solution is also saturated with lithium sulfide. Both of these measures minimize the dissolution of the electrode components. For their anode (positive electrode), Scrosati and Hassoun selected nanoscopic tin particles that are enclosed in a protective carbon matrix.

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